|
Search | Add a publication |
| ID No : | 666 Edit | Title: | Performance Testing of Molten Regolith Electrolysis with Transfer of Molten Material for the Production of Oxygen and Metals on the Moon |
| Summary / Review : | "Previously, we have demonstrated the production of oxygen by electrolysis of molten regolith simulants at temperatures near 1600 C. Using an inert anode and suitable cathode, direct electrolysis (no supporting electrolyte) of the molten silicate is carried out, resulting in the production of molten metallic products at the cathode and oxygen gas at the anode. Initial direct measurements of current efficiency have confirmed that the process offer potential advantages of high oxygen production rates in a smaller footprint facility landed on the moon, with a minimum of consumables brought from Earth. We now report the results of a scale-up effort toward the goal of achieving production rates equivalent to 1 metric ton O2/year, a benchmark established for the support of a lunar base. We previously reported on the electrochemical behavior of the molten electrolyte as dependent on anode material, sweep rate and electrolyte composition in batches of 20-200g and at currents of less than 0.5 A. In this paper, we present the results of experiments performed at currents up to 10 Amperes) and in larger volumes of regolith simulant (500 g - 1 kg) for longer durations of electrolysis. The technical development of critical design components is described, including: inert anodes capable of passing continuous currents of several Amperes, container materials selection, direct gas analysis capability to determine the gas components co-evolving with oxygen. To allow a continuous process, a system has been designed and tested to enable the withdrawal of cathodically-reduced molten metals and spent molten oxide electrolyte. The performance of the withdrawal system is presented and critiqued. The design of the electrolytic cell and the configuration of the furnace were supported by modeling the thermal environment of the system in an effort to realize a balance between external heating and internal joule heating. We will discuss the impact these simulations and experimental findings have on the design of a suitable prototype for lunar applications" (Author's abstract) |
| Author(s) : |
Sibille, Laurent; Sadoway, Donald; Tripathy, Prabhat; Standish, Evan; Sirk, Aislinn; Melendez, Orlando; Stefanescu, Doru, [Kennedy Space Center] |
| Publication Date: | 2010 |
| Category(s) : |
Bases, industry and manufacturing / Resource processing and outputs / Electrolysis |
| Progress Type: | D ( A=Analysis only, D=Design, T=Testing, C=Completed or Commercial product ) |
| Web URL : |
http://hdl.handle.net/2060/20110008524
If this link is broken, please Add Comment below. We try to keep author contact details, and a backup copy in our offline library. |
| PERMANENT code(s) : | L,U |
|
(Explanation of the last 3 rows above) |
In the row above, there are up to 4 possibilities: U = URL you can click on to get a copy instantly from another source on the internet, or request it from that source D = Downloadable from PERMANENT (such as because no other URL known...) L = LAN copy, PERMANENT has a digital copy but not downloadable from our website P = Paper copy in the PERMANENT office Typically, only 0 to 3 methods are available. |
| NTRS : | 20110008524 |
| Other Ref # : | KSC-2009-310 |
| Submitted by : | MEP |
| Comments: |
Please add your thoughtful Comments to this paper after reading it. All comments are reviewed and approved before being posted publicly below. If you wish to submit a private comment to the curator, instead of a public comment, just write "Private" at the start of your comment. Corrections and suggested additions to our records are appreciated. |
Add Comment |